Aluminum

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Categories: Periodic Element

AluminumType: Mineral
Periodic Element: (Al)
RDA: None listed
Importance- To Body:
Generally considered hazardous or detrimental biologically. Aluminium increases estrogen-related gene expression in human breast cancer cells cultured in the laboratory. The estrogen-like effects of these salts have led to their classification as metalloestrogens.
Distribution- In Body:
In very high doses, aluminium is associated with altered function of the blood–brain barrier. Consumption of acidic foods or liquids with aluminium enhances aluminium absorption, and maltol has been shown to increase the accumulation of aluminium in nerve and bone tissues.
Excess Effects:
Some People experience allergic reactions to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium such as antiperspirants and antacids.
Otherwise, there is evidence of some toxicity if it is consumed in amounts greater than 40 mg/day per kg of body mass. Excessive consumption of antacids containing aluminium compounds and excessive use of aluminium-containing antiperspirants provide more significant exposure levels.
Exposure to powdered aluminium or aluminium welding fumes can cause pulmonary fibrosis.
Deficiency Effects:
None listed
Sources Food:
Some studies point to risks associated with increased exposure to the metal. Aluminium in food may be absorbed more than aluminium from water.
Sources Environmental/Geographic:
(OSHA) has set a permissible exposure limit of 15 mg/m3 time weighted average (TWA) for total exposure and 5 mg/m3 TWA for respiratory exposure. The US National Institute for Occupational Safety and Health (NIOSH) recommended exposure limit is the same for respiratory exposure but is 10 mg/m3 for total exposure, and 5 mg/m3 for fumes and powder.
Supplement Information:
Research correlating Aluminum as a factor in Alzheimer’s is inconclusive; aluminium accumulation may be a consequence of the disease rather than a causal agent.

Aluminum (Wikipedia)
Aluminium,  13Al
Aluminium-4.jpg
General properties
Pronunciation
Alternative name aluminum (U.S., Canada)
Appearance silvery gray metallic
Standard atomic weight (Ar, standard) 26.9815385(7)
Aluminium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
B

Al

Ga
magnesiumaluminiumsilicon
Atomic number (Z) 13
Group group 13 (boron group)
Period period 3
Element category   post-transition metal, sometimes considered a metalloid
Block p-block
Electron configuration [Ne] 3s2 3p1
Electrons per shell
2, 8, 3
Physical properties
Phase at STP solid
Melting point 933.47 K ​(660.32 °C, ​1220.58 °F)
Boiling point 2743 K ​(2470 °C, ​4478 °F)
Density (near r.t.) 2.70 g/cm3
when liquid (at m.p.) 2.375 g/cm3
Heat of fusion 10.71 kJ/mol
Heat of vaporization 284 kJ/mol
Molar heat capacity 24.20 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1482 1632 1817 2054 2364 2790
Atomic properties
Oxidation states +3, +2, +1, −1, −2 ​(an amphoteric oxide)
Electronegativity Pauling scale: 1.61
Ionization energies
  • 1st: 577.5 kJ/mol
  • 2nd: 1816.7 kJ/mol
  • 3rd: 2744.8 kJ/mol
  • (more)
Atomic radius empirical: 143 pm
Covalent radius 121±4 pm
Van der Waals radius 184 pm
Color lines in a spectral range
Miscellanea
Crystal structure face-centered cubic (fcc)
Face-centered cubic crystal structure for aluminium
Speed of sound thin rod (rolled) 5000 m/s (at r.t.)
Thermal expansion 23.1 µm/(m·K) (at 25 °C)
Thermal conductivity 237 W/(m·K)
Electrical resistivity 28.2 nΩ·m (at 20 °C)
Magnetic ordering paramagnetic
Magnetic susceptibility +16.5·10−6 cm3/mol
Young's modulus 70 GPa
Shear modulus 26 GPa
Bulk modulus 76 GPa
Poisson ratio 0.35
Mohs hardness 2.75
Vickers hardness 160–350 MPa
Brinell hardness 160–550 MPa
CAS Number 7429-90-5
History
Naming after alumina (aluminium oxide), itself named after mineral alum
Prediction Antoine Lavoisier (1782)
Discovery and first isolation Hans Christian Ørsted (1824)
Named by Humphry Davy (1812)
Main isotopes of aluminium
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
26Al trace 7.17×105 y β+ 26Mg
ε 26Mg
γ
27Al 100% stable
| references | in Wikidata

Aluminium or aluminum is a chemical element with symbol Al and atomic number 13. It is a silvery-white, soft, nonmagnetic and ductile metal in the boron group. By mass, aluminium makes up about 8% of the Earth's crust; it is the third most abundant element after oxygen and silicon and the most abundant metal in the crust, though it is less common in the mantle below. The chief ore of aluminium is bauxite. Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is found combined in over 270 different minerals.

Aluminium is remarkable for its low density and its ability to resist corrosion through the phenomenon of passivation. Aluminium and its alloys are vital to the aerospace industry and important in transportation and building industries, such as building facades and window frames. The oxides and sulfates are the most useful compounds of aluminium.

Despite its prevalence in the environment, no known form of life uses aluminium salts metabolically, but aluminium is well tolerated by plants and animals. Because of these salts' abundance, the potential for a biological role for them is of continuing interest, and studies continue.

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