Sulfur

Sulfur,  ₁₆S

General properties
Alternative name	sulphur (British spelling)
Appearance	lemon yellow sintered microcrystals
Standard atomic weight (Ar, standard)	[7001320590000000000♠32.059, 7001320760000000000♠32.076] conventional: 7001320600000000000♠32.06
Sulfur in the periodic table
Hydrogen Helium Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson O ↑ S ↓ Se phosphorus ← sulfur → chlorine
Atomic number (Z)	16
Group	group 16 (chalcogens)
Period	period 3
Element category	polyatomic nonmetal
Block	p-block
Electron configuration	[Ne] 3s2 3p4
Electrons per shell	2, 8, 6
Physical properties
Phase at STP	solid
Melting point	388.36 K ​(115.21 °C, ​239.38 °F)
Boiling point	717.8 K ​(444.6 °C, ​832.3 °F)
Density (near r.t.)	alpha: 2.07 g/cm3 beta: 1.96 g/cm3 gamma: 1.92 g/cm3
when liquid (at m.p.)	1.819 g/cm3
Critical point	1314 K, 20.7 MPa
Heat of fusion	mono: 1.727 kJ/mol
Heat of vaporization	mono: 45 kJ/mol
Molar heat capacity	22.75 J/(mol·K)
Vapor pressure P (Pa) 1 10 100 1 k 10 k 100 k at T (K) 375 408 449 508 591 717
Atomic properties
Oxidation states	6, 5, 4, 3, 2, 1, −1, −2 ​(a strongly acidic oxide)
Electronegativity	Pauling scale: 2.58
Ionization energies	1st: 999.6 kJ/mol 2nd: 2252 kJ/mol 3rd: 3357 kJ/mol (more)
Covalent radius	105±3 pm
Van der Waals radius	180 pm
Spectral lines
Miscellanea
Crystal structure	​orthorhombic
Thermal conductivity	0.205 W/(m·K) (amorphous)
Electrical resistivity	2×1015  Ω·m (at 20 °C) (amorphous)
Magnetic ordering	diamagnetic
Magnetic susceptibility	(α) −15.5·10−6 cm3/mol (298 K)
Bulk modulus	7.7 GPa
Mohs hardness	2.0
CAS Number	7704-34-9
History
Discovery	Chinese(before 2000 BCE)
Recognized as an element by	Antoine Lavoisier (1777)
Main isotopes of sulfur
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct 32S 94.99% stable 33S 0.75% stable 34S 4.25% stable 35S trace 87.32 d β− 35Cl 36S 0.01% stable
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Sulfur is a chemical element with symbol S and atomic number 16. It is abundant, multivalent, and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S₈. Elemental sulfur is a bright yellow crystalline solid at room temperature. Chemically, sulfur reacts with all elements except for gold, platinum, iridium, tellurium, and the noble gases.

Sulfur is the tenth most common element by mass in the universe, and the fifth most common on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and Egypt. In the Bible, sulfur is called brimstone. Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum. The greatest commercial use of the element is the production of sulfuric acid for sulfate and phosphate fertilizers, and other chemical processes. The element sulfur is used in matches, insecticides, and fungicides. Many sulfur compounds are odoriferous, and the smells of odorized natural gas, skunk scent, grapefruit, and garlic are due to organosulfur compounds. Hydrogen sulfide gives the characteristic odor to rotting eggs and other biological processes.

Sulfur is an essential element for all life, but almost always in the form of organosulfur compounds or metal sulfides. Three amino acids (cysteine, cystine, and methionine) and two vitamins (biotin and thiamine) are organosulfur compounds. Many cofactors also contain sulfur including glutathione and thioredoxin and iron–sulfur proteins. Disulfides, S–S bonds, confer mechanical strength and insolubility of the protein keratin, found in outer skin, hair, and feathers. Sulfur is one of the core chemical elements needed for biochemical functioning and is an elemental macronutrient for all living organisms.